Emergy as a tool for Ecodesign: evaluating materials selection for beverage packages in Brazil

The life of a product begins with the initial product design concepts; the costs and potential impacts of a product are heavily influenced by the final design, the production processes, the economic and environmental costs of all raw materials. Additionally, both of these factors are very much affected by how the products are managed during and after consumer usage. Thus, there is an urgent need for a tool to facilitate the integration and assessment of environmental and economic demands into the product planning and development processes. The introduction of environmental accounting based on emergy as a tool to assist in product design is proposed. This complementary tool may be inserted into the conventional design methodology to facilitate in the selection of materials and processes as well as in the actual design of the products. To illustrate the application of the proposed method for material selection, PET (polyethylene terephthalate) bottles and aluminum cans for beverage packaging are compared. Despite the exceptional condition of aluminum recycling in Brazil, results show that the best option for beverage packages is the PET bottles.     

Sustainability assessment of a giant bamboo plantation in Brazil: exploring the influence of labour,time and space

Bamboo presents physical and mechanical characteristics, which turn it an alternative option for product development, replacing native or reforested wood. The sustainability assessment of a Dendrocalamus Giganteus species plantation in Brazil through the emergy methodology evidences a great weight of renewable (30% sej/sej) and human labour contributions (33% sej/sej). These contributions account for the great interface with environment and to the intensive work, respectively. The transformity value of bamboo production is 2.42E + 04 sej/J. The influence human labour has on the total emergy flow and on indicators is evaluated by taking into account different country locations (Brazil, Australia and China). Thus, a different transformity value for labour is assumed for each country. A ranking based on emergy sustainability index (ESI) values shows that bamboo production in China was the first placed, followed by Brazil and Australia (values of 1.18, 0.50 and 0.09, respectively). The insertion of indirect renewability embedded in labour results in the ranking modification, leading to plantation in Brazil in the first place, followed by the Australian and Chinese ones. The relative position of the bamboo systems is visualized in the ternary diagram expressed in terms of emergy. In an attempt to explore the relationship between sustainability and time, a graphic of ESI vs. global productivity is discussed in terms of a prospective evaluation. Indirect support areas of the bamboo production are calculated as a way to evaluate the sustainability-space relationship.     

Canopy profiles of photosynthetic parameters under elevated CO2 and N fertilization in a poplar plantation

A poplar plantation has been exposed to an elevated CO2 concentration for 5 years using the free air CO2 enrichment (FACE) technique. Even after such a long period of exposure, leaves of Populus x euramericana have not shown clear signs of photosynthetic acclimation. Only at the end of the growing season for shade leaves was a decrease of maximum velocity of carboxylation (Vcmax) observed. Maximum electron transport rate (Jmax) was increased by FACE treatment in July. Assimilation rates at CO2 partial pressure of 400 (A400) and 600 (A600) micromol mol(-1) were not significantly different under FACE treatment. Most notably FACE significantly decreased stomatal conductance (g(s)) both on upper and lower canopy leaves. N fertilization increased N content in the leaves on mass basis (Nm) and specific leaf area (SLA) in both CO2 treatments but did not influence the photosynthetic parameters. These data show that in poplar plantations the long-term effects of elevated CO2 on photosynthesis do not differ considerably from the short-term ones even with N deposition.     

Coupling of 2,4,6-trinitrotoluene (TNT) metabolites onto humic monomers by a new laccase from Trametes modesta

During degradation of trinitrotoluene (TNT) by Trametes modesta, addition of humic monomers prevented the accumulation of all major stable TNT metabolites (aminodinitrotoluenes [AMDNT]) by at least 92% in the presence of 200 mM ferulic acid and guaiacol. Acute toxicity tests with individual TNT metabolites and in T. modesta cultures supplemented with 200 microM TNT demonstrated that the TNT biodegradation process lead to less toxic metabolites. Toxicity decreased in the order TNT>4-HADNT (4-hydroxylaminodinitrotoluene)>2-HADNT>2,6-DNT (2,6-dinitrotoluene)>2',2',6,6-azoxytetranitrotoluene>4-AMDNT>2-AMDNT>2,4-diamninonitrotoluene (2,4-DAMNT) while 2,4-DNT and 2,6-DAMNT were the least toxic. Ferulic acid is the best candidate for immobilization TNT biodegradation metabolites since it prevented the accumulation of AMDNTs in cultures during TNT biodegradation and its products were less toxic. All humic monomers were very effective in immobilizing 2-HADNT [100%], 4-HADNT [100%] and 2,2,6,6-azoxytetranitrotoluene [100%]. Two distinct laccase isoenzymes (LTM1 and LTM2) potentially involved in immobilization of TNT degradation products were purified to electrophoretic homogeneity. LTM1 and LTM2 have molecular weights of 77.6 and 52.5 kDa, are 18% and 24% glycosylated, have pI values of 3.6 and 4.2, respectively. Both enzymes oxidized all the typical laccase substrates tested. LTM1 showed highest kinetic constants (K(m)=0.03 microM; K(cat)=8.8 4x 10(7)s(-1)) with syringaldazine as substrate.     

Biodegradation studies of selected priority acidic pesticides and diclofenac in different bioreactors

The biodegradation of selected priority acidic pesticides MCPP, MCPA, 2,4-D, 2,4-DP and bentazone and the acidic pharmaceutical diclofenac was investigated using a membrane bioreactor (MBR) and a fixed-bed bioreactor (FBBR). A pilot plant MBR was fed with raw water spiked with the selected compounds. The experiment was repeated every week during four weeks to enhance the adaptation of microorganisms. In order to further study the biodegradability of these compounds, degradation studies in a FBBR were carried out. All the samples were analysed by solid phase extraction-gas chromatography-mass spectrometry (SPE-GC-MS). The results indicate that in the MBR compounds except for bentazone were eliminated within the first day of the experiment at rates ranging from 44% to 85%. Comparing these results with the degradation rates in the FBBR showed that in the latter only MCPP, MCPA 2,4-D and 2,4-DP were degraded after a much longer adaptation phase of microorganisms.     

Long-term study of environmental levels of dioxins and furans in the vicinity of a municipal solid waste incinerator

From 1975 to 2004, a municipal solid waste incinerator (MSWI) was operating in Montcada (Barcelona, Catalonia, Spain). Because of the potential health risks derived from emission of pollutants by the facility, especially polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs), a long-term monitoring program focused on measuring the environmental levels of PCDD/Fs near the facility, and to assess the health risks for the population living in the neighborhood, was established between 1996 and 2002. A total number of 111 soil and 121 herbage samples were analyzed for PCDD/Fs during this period. Human health risks for the individuals living near the MSWI (500 and 1,000 m) were also assessed before (1998) and after modernization (2000) of the facility. It included PCDD/F inhalation, dermal contact, soil and dust ingestion, and food intake. All these data are here summarized. The environmental levels of PCDD/Fs showed that the MSWI was not the main responsible of the atmospheric pollution by these compounds. In turn, human health risks for the population living in the vicinity of the facility after introduction of a modern technology were negligible in comparison with the dietary PCDD/F exposure.     

Working conditions,psychological/physical symptoms and occupational accidents. Bayesian network models

Each day thousands of workers suffer occupational accidents of varying degrees of severity. Accidents at work render workers incapable of carrying out their day to day activities, either temporarily or permanently, and they also have detrimental effects on family life, the company, and the general public. In order to reduce the occupational accident rate, it is necessary to determine the causes of those accidents. Although there are many different types of accidents, they generally stem from poor working conditions. The purpose of this study was to analyze the influence of working conditions on occupational accidents from data gathered in the VI National Survey of Working Conditions (VI NSWCs) in 2007. This survey utilized a random sample of the active population of Spain. The sample comprised 11,054 people (5917 males and 5137 females). In order to carry out the study, a probabilistic model was built using Bayesian networks. The model included the following variables: hygiene conditions, ergonomic conditions, job demands, physical symptoms, psychological symptoms, and occupational accidents. The study demonstrated that there were strong relationships between hygiene conditions and occupational accidents; it has been shown that poor hygienic conditions duplicate the probability of accident. Physical symptoms increased almost 50% due to poor ergonomic conditions. And finally, high job demands almost duplicated the psychological symptoms. The investigation also showed a high degree of interdependence between physical and psychological symptomatologies and the relationship between these and occupational accidents.     

Perceived changes in well-being and happiness with gardening in urban organic allotments in Portugal

Urban allotment gardens (AG) in Portugal have increased in recent years, as in many other European countries and worldwide. The contribution of these gardens to the happiness and well-being of urban populations has been recognized, but evaluations of their benefits are still very scarce. The objective of this study was to evaluate this contribution, based on the urban organic AG of the Devesa Park in Vila Nova de Famalicão, Portugal. The sample included 65 gardeners who completed the self-administered questionnaires of Bem-Estar Pessoal (personal well-being scale), Felicidade Subjetiva (subjective happiness scale) and sociodemographic characteristics. Respondents were mainly adults under 65 years, married and academically well qualified and about half of them had a professional activity, with nearly one third being retired. They considered themselves happy with their life (Personal Well-being Index = 74.5%) and revealed an optimistic and positive attitude towards life, regardless of economic or social difficulties. The increased frequency of visits for gardening was positively related to a greater perception of subjective happiness. The gardeners who visited the AG more frequently considered themselves happier from a self-perspective and in comparison with peers. It can be suggested that urban organic AG represent a means for enhancing citizen well-being, contributing positively to their feelings of happiness and life satisfaction, changing behaviours and developing personal capacities. Beyond economic measures, urban AG can be recommended to capture the well-being of societies.     

Life cycle assessment tool of electricity generation in Portugal

This paper investigates multi-stakeholder arrangements initiated by businesses and NGOs from the North that aim to enhance a more sustainable agricultural production at specific localities in Southern countries. We aim to better understand the search for concerted action in multi-actor arrangements. Therefore, this paper presents a diagnostic framework with three strategic challenges the partnership projects are facing: linking global economic objectives to local needs, values and interests; bridging public and private interests and responsibilities; and seeking trade-offs between social, environmental and economic values. Starting from the partnerships’ Theory of Change, this diagnostic framework is applied to comparative case studies of partnership projects in the cocoa sector in Indonesia, which are part of a Northern-based public–private partnership to improve farmers’ prospective. It is concluded that the economic reality faced by the farmers differs from that of the Northern actors; collaboration with governments is difficult because of different organizational cultures; and the partnership projects underestimate the strength of vested social relations the smallholders are part of. Overall, the initiators of the partnerships seem to work with a too restricted economic interpretation of the local reality.